TEXTILE CHEMISTRY

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Friday, 29 December 2017

Acrylic Printing



Printing of Acrylic by Direct Style

Principle
           
Acrylic fabric can be printed with cationic dye as per the dyeing procedure.
ð  Printing of Acrylic is differs from dyeing as below:-
·         Dyes of various (Cationic/Basic) classes can be used in combination with each other.
·         No blocking effect occurs.
·         Colour build up is better.

Ingredients

(1)   Dyes:-
·         Cationic, disperse and vat dyes are suitable for printing acrylic fibres.
·         Cationic dyes are the most important and most widely used class of dyes for printing of acrylic fabric.
·         Prints produced with cationic dyes have excellent wet and rubbing fastness.
·         Disperse dyes give dull shades when printed on acrylic fabric.
·         Sharp outline with black colour is produced using disperse dyes only.

(2)   Thickeners:-
·         Thickeners having high solid content are best suitable for this printing.
·         Modified gaur gum, tragacanth, British gum etc. are suitable thickeners for printing of acrylic
·         Since the fabric is hydrophobic in nature thickener selection is important factor.
·         Modified guar gum is alkaline in nature and hence has to be neutralised with acid.
·         British gum – gum tragcanth mixtures perform well.

(3)   Swelling agent:-
·         To increase the diffusion of dyes in the fibre and colour value, fibre swelling agents are added in the paste.
·         Excessive use of swelling agents may result in increased bleeding of dyes.
·         Eg. Resorcinol, Phenol

(4)   Wetting agent or Solvent:-
·         Thiodiethylene glycol is a solvent for the cationic dyes, some of which may be sparingly soluble in water, especially at low temperature.
·         Addition of swelling and oxidising agent decreases the solubility of the dye, hence addition of solvent is desirable.

(5)   Acid:-
·         Paste contains acetic acid as well as tartaric acid to improve the solubility of the dyes and to adjust the pH of paste.
·         Since acetic acid is lost by evaporation during drying of the prints, non-volatile acid (tartaric acid) supplies the necessary acidity during steaming.

(6)   Oxidising agent:-
·         Sodium chlorate is used to protect the brightness of the dye against any possible reduction of the dye under the prolonged steaming conditions.

Procedure

·         The printing paste is prepared as follows:-

      50  parts    Cationic (Basic) dye
                              20 parts     Acetic acid (50 %)
                      20 – 30 parts     Thidiethylene glycol
                      20 – 30 parts     Tartaric acid
                            165 parts    Water
                                5  parts    Sodium chlorate
                            680  parts    Thickener
                              20 parts    Resorcinol/Phenol
                          1000  parts

·         After printing, fabric is dried and steamed in star ager at 103ºC for 40 minutes.
·         A temperature of 105ºC is the maximum allowable steaming temperature.
·         If it exceeds 105ºC undesirable effects like alteration of hand, bleeding, increased fabric shrinkage etc. result.
·         The steamed fabric is after treated with a bath containing 1 to 2 gpl anionic detergent at 60ºC for 30 minutes.
·         Finally, the cloth is rinsed, washed and dried.

3 comments:

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